Ordered alignment of a one-dimensional π-conjugated nickel bis(dithiolene) complex polymer produced via interfacial reactions.

نویسندگان

  • Ryota Matsuoka
  • Ryota Sakamoto
  • Tetsuya Kambe
  • Kenji Takada
  • Tetsuro Kusamoto
  • Hiroshi Nishihara
چکیده

A liquid-liquid interfacial synthesis using 1,2,4,5-benzenetetrathiol and nickel(II) ions produced a thin black film of a π-conjugated polymer featuring the nickel bis(dithiolene) motif. Its ordered structure was not originally identified due to its amorphicity; however, it was observed to align regularly on a highly oriented pyrolytic graphite substrate using scanning tunnelling microscopy.

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عنوان ژورنال:
  • Chemical communications

دوره 50 60  شماره 

صفحات  -

تاریخ انتشار 2014